Adsorption Mechanism and Kinetic Characterization of Bituminous Coal under High Temperatures and Pressures in the Linxing-Shenfu Area     

TAO Chuanqi  WANG Yanbin  LI Yong  NI Xiaoming  GAO Xiangdong 《《地质学报》英文版》2020,94(2):399-408

The majority of coalbed methane(CBM) in coal reservoirs is in adsorption states in coal matrix pores. To reveal the adsorption behavior of bituminous coal under high-temperature and high-pressure conditions and to discuss the microscopic control mechanism affecting the adsorption characteristics, isothermal adsorption experiments under hightemperature and high-pressure conditions, low-temperature liquid nitrogen adsorption-desorption experiments and CO2 adsorption experiments were performed on coal samples. Results show that the adsorption capacity of coal is comprehensively controlled by the maximum vitrinite reflectance(Ro, max), as well as temperature and pressure conditions. As the vitrinite reflectance increases, the adsorption capacity of coal increases. At low pressures, the pressure has a significant effect on the positive effect of adsorption, but the effect of temperature is relatively weak. As the pressure increases, the effect of temperature on the negative effect of adsorption gradually becomes apparent, and the influence of pressure gradually decreases. Considering pore volumes of pores with diameters of 1.7-100 nm, the peak volume of pores with diameters 10-100 nm is higher than that from pores with diameters 1.7-10 nm, especially for pores with diameters of 40-60 nm, indicating that pores with diameters of 10-100 nm are the main contributors to the pore volume. The pore specific surface area shows multiple peaks, and the peak value appears for pore diameters of 2-3 nm, indicating that this pore diameter is the main contributor to the specific surface area. For pore diameters of 0.489-1.083 nm, the pore size distribution is bimodal, with peak values at 0.56-0.62 nm and 0.82-0.88 nm. The adsorption capability of the coal reservoir depends on the development degree of the supermicroporous specific surface area, because the supermicroporous pores are the main contributors to the specific pore area. Additionally, the adsorption space increases as the adsorption equilibrium pressure increases. Under the same pressure, as the maximum vitrinite reflectance increases, the adsorption space increases. In addition, the cumulative reduction in the surface free energy increases as the maximum vitrinite reflectance increases. Furthermore, as the pressure increases, the surface free energy of each pressure point gradually decreases, indicating that as the pressure increases, it is increasingly difficult to adsorb methane molecules.  相似文献   

井喷关井水击分析及水击波速计算          下载免费PDF全文

史富全 《探矿工程》2020,47(11):37-43

油气井发生溢流或井喷后，立即关闭防喷器，关井期间防喷器需经受关井产生的水击压力作用。本文在对井喷关井水击的传播物理特征分析的基础上，推导直接关井水击压力计算公式，综合考虑井筒流体含气率、气液两相流型、固相类型等对水击波速的影响，推导水击波在气、液、固三相混合流体中传播速度计算公式，并通过算例对水击波速影响因素进行分析。计算表明水击波速对含气率变化非常敏感，钻井液含气率在0～0.001的时候，水击波速几乎是发生了突变，水击波速在含气率为0.001时仅为385 m/s，相比纯钻井液情况下降了67%，而钻井液固相含量、套管的内径和壁厚对水击波传播速度影响较小。  相似文献   

中国草畜平衡状态时空演变指示的草地生态保护格局   总被引：2，自引：0，他引：2  

黄麟  翟俊  祝萍  郑瑜晗 《地理学报》2020,75(11):2396-2407

中国草原牧区作为重要生态安全屏障和草地畜牧业生产基地,其草畜平衡状态直接影响草地退化与恢复,进而影响草地生态系统服务能力的强弱。本文分析了2000—2015年主要草原牧区草地植被覆盖、牧草供给、草畜平衡状态的时空变化特征,深入探讨草地退化与恢复及载畜压力下草地生态系统保护与恢复空间格局。结果表明：过去16年主要草原牧区草地面积净减少约163万hm²,6.7%的草地出现植被覆盖退化,而5.4%的草地呈现植被覆盖明显恢复。天然草地牧草供给量以增加为主,年增率约0.3 kg/hm²,然而其载畜压力亦持续增加,不考虑补饲的载畜压力指数高达3.8,除内蒙古东北部、青藏高原中部仍有载畜潜力,其余多处于超载状态;考虑实际冷季补饲的载畜压力指数约3.1,内蒙古中东部有所缓解;假设冷季全额补饲则载畜压力指数减至1.9,内蒙古、青藏高原等区域明显缓解。叠加上述数据,本文针对自然保护地、牧区、半农半牧区和农区等不同区域的草地生态保护格局,提出了平衡草地生态保护与畜牧生产利用的不同发展策略。  相似文献   

建筑在强震下横拉承压力钢筋负荷测量          下载免费PDF全文

任燕娟 《地震工程学报》2018,40(4):692-697

在强震状态下,建筑物的横拉承压受力较为复杂,另外由于建筑物形状及在地震中受力面积大小不同,在强震下造成碰撞大小影响不一导致其横拉承压力的随机复杂性十分突出。传统的建筑承压负荷检测方法中钢筋负荷受力测量能力不足,检测结果易出现误差。将建筑钢筋的机械性能设为理想弹塑性,利用建筑物横拉承压力钢筋负荷测量方法,对不同结构、不同工况的建筑钢筋载荷的变化规律进行测试分析,结合建筑局部承压特点和整体结构聚力方式,设计横拉承压力钢筋负荷检测方法,并进行仿真实验,结果表明该方法模型所得数据更加精准,有良好的适用性。  相似文献   

捷联式航空重力扰动矢量解算及误差补偿     

郭栋  孙中苗  吴富梅  张琪 《大地测量与地球动力学》2018,38(12):1295-1301

介绍捷联式航空重力矢量测量的基本原理，利用波数相关滤波（WCF）、比力线性校正的方法对重力扰动的水平和垂向分量进行误差补偿，评定内符合精度。对国产捷联式航空重力矢量仪的某次试验数据进行处理，以验证和评估航空重力矢量仪的性能。结果表明，在半波长分辨率为7.5 km时，6条重复测线的重力扰动水平分量经波数相关滤波处理后，东、北向分量的平均内符合精度分别从9.77 mGal、9.18 mGal提高到5.95 mGal、3.83 mGal；对比力的垂向分量线性校正后，将解算的重力扰动垂向分量再用WCF方法处理，其平均内符合精度从1.27 mGal提高到0.59 mGal。  相似文献   

高温高压条件下彭灌杂岩的强度对汶川地震发震机制的启示   总被引：1，自引：1，他引：0       下载免费PDF全文

牛露  周永胜  姚文明  邵同宾  马玺  党嘉祥  何昌荣 《地球物理学报》2018,61(5):1728-1740

采用汶川地震震源区彭灌杂岩中代表性细粒花岗岩样品，在固体围压介质三轴实验系统上开展了高温高压流变实验研究.实验的温度和压力条件按照龙门山断层带5~30 km深度对应的温度和压力（静岩压）设定.利用偏光显微镜和扫描电镜对实验样品进行微观结构观察.实验结果表明，实验样品在10~20 km深度都具有很高的强度，彭灌杂岩在该深度处于脆性破裂-脆塑性转化域，而在20~30 km实验样品强度显著降低，彭灌杂岩进入塑性流变域，这与流变结构中的极限强度很接近.以花岗岩为代表的彭灌杂岩的破裂强度决定了中上地壳的强度，在15~20 km深度不仅强度达到最大值，而且控制了断层不稳定滑动，具备地震成核条件.因此，把彭灌杂岩强度随深度变化规律与流变结构和滑动稳定性参数（a-b）结合起来得出，彭灌杂岩在15~20 km的高强度是汶川地震的孕育和发生的必要条件.  相似文献   

近距离上层隧道施工对下层隧道的扰动影响          下载免费PDF全文

唐强森  刘涛 《地震工程学报》2018,40(3):591-596,603

针对近距离上层隧道施工时给下层隧道稳定性造成扰动影响的现状,基于简支土体梁力学模型,研究下层隧道顶部在周期性扰动力作用下的系统振动特性,得到顶部垂直位移的动态响应数学表达式,为定量掌握最大位移峰值的大小与出现时刻提供理论依据,指出考虑振动因素时上下层隧道安全距离的确定方法。结合具体算例探索扰动力等因素对最大位移的作用规律,结果表明:扰动力振幅和隧道跨度分别增加1倍和2倍时,最大位移峰值相应增大1倍和23.9倍;隧道层间垂距和土体弹性模量分别增加2倍和3倍时,最大位移峰值相应减小88.2%和70%。当主要影响因素变化时,最大位移的波动大周期延长、波动震荡性加剧,特别是峰值处的震荡幅值增大,隧道顶部稳定性受到明显影响。  相似文献   

Geomorphic effectiveness: a linear concept in a non‐linear world          下载免费PDF全文

Peyton E. Lisenby  Jacky Croke  Kirstie A. Fryirs 《地球表面变化过程与地形》2018,43(1):4-20

Geomorphic effectiveness has been an influential concept in geomorphology since its introduction by Reds Wolman and John Miller in 1960. It provided a much needed framework to assess the significance of an event by comparing event magnitude to the resultant geomorphic effects. Initially, this concept was applied primarily in river channels, under the linear assumption that geomorphic responses to similarly sized flood events will be consistent. Numerous authors have since attempted to quantify a direct, proportional relationship between event magnitude and different forms of geomorphic response in a variety of geomorphic settings. In doing so, these investigations applied an array of metrics that were difficult to compare across different spatiotemporal scales, and physiographic and geomorphic environments. Critically, the emergence of other geomorphic concepts such as sensitivity, connectivity, thresholds, and recovery has shown that relationships between causes (events) and geomorphic effects (responses) are often complex and non‐linear. This paper disentangles the complex historical development of the geomorphic effectiveness concept and reviews the utility of various metrics for quantifying effectiveness. We propose that total energy (joules) is the most appropriate metric to use for quantifying the magnitude of disturbance events (cause) and volumetric sediment flux associated with landform modification is the most appropriate metric for quantifying geomorphic effects. While both metrics are difficult to quantify, they are the only ones which facilitate comparison across a range of spatiotemporal scales (comparability) in a variety of geomorphic environments (flexibility). The geomorphic effectiveness concept can continue to be useful provided that geomorphologists use flexible and comparable metrics. Today, geomorphologists are better prepared to consider the influence of non‐linear processes on determinations of geomorphic effectiveness, allowing investigators to not only determine if a disturbance event was effective but also to explain why or why not. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   

无人船运动控制方法综述   总被引：1，自引：1，他引：0  

裴志远  戴永寿  李立刚  金久才  邵峰 《海洋科学》2020,44(3):153-162

为实现无人船海上自主作业,无人船运动控制的快速性、准确性以及鲁棒性亟待提高。首先从全驱动控制和欠驱动控制角度,分别概括了国内外无人船航向控制、航速控制、轨迹跟踪控制以及路径跟踪控制的主流控制方法。其次,归纳总结了处理海洋环境不确定扰动的研究进展,包括扰动的建模和消除、抑制扰动的主流方法。最后,总结了无人船运动控制现状与存在的问题,并从工程应用和理论研究两个角度对未来的研究方向进行了展望。  相似文献   

Effect of microstructure on stress–strain and pore-pressure response of sabarmati sand under the influence of mica     

P. Seethalakshmi 《Geomechanics and Geoengineering》2020,15(2):123-139

ABSTRACT

Micaceous soil is believed to be detrimental for civil engineering constructions due to the effect of high compressibility, low compacted density and low shear strength. Individual mica particle has numerous intact mica flakes foliated over each other making it flexible upon loading and rebound upon unloading due to its low hardness and resilient nature. Hence, micaceous soils with mica content more than 10% are considered undesirable for highway pavements, embankments and railway track constructions. When platy mica particles are sufficiently numerous to interact with spherical sand particles, bridging and ordering phenomena are augmented within the soil mass creating unique sand-mica particle orientation (MS microstructure) unlike sand-sand particle orientation (PS microstructure). The current experimental research was conducted to evaluate the variation in stress–strain, pore pressure and effective stress path response of Sabarmati sand under the influence of mica (sand with 30% mica and pure sand) with MS and PS microstructure respectively. Effect of particle crushing on stress–strain and pore pressure response was also studied on Sabarmati sand with MS and PS microstructure. Distinctive macroscopic response was observed in Sabarmati sand with MS microstructure under the influence of mica as well as mica particle crushing.  相似文献